Saturday, May 7, 2011

Chem II: Final Exam Review (Part 4/4)


Nuclear Chemistry

1.       What is the A,X,Z of an atom? A = Mass Number, X = Element, Z = Protons (Atomic #)
2.       What are the 5 types of spontaneous radioactive decay?

Name & Sym
Particle
Formula
Z#
A#
Reason
Alpha α
42He
-
-2
-4
Z > 83
Beta β-
0-1e
10n --> 11p + 0-1e
+1
0
N/Z too large
Positron β+
0+1e
11p --> 10n + 0+1e
-1
0
N/Z too small
Electron Cap. (EC)
X rays
11p + 0-1e --> 10n
-1
0
N/Z too small
Gamma  γ
00 γ
-
0
0
Excited

3.       What is the highest non-radioactive atomic number?      - 83
4.       What are the magic numbers of stability?
a.       For Protons?      2, 8, 20 , 28, 50, 82
b.      For Neutrons?   2, 8, 20, 28, 50, 82, 126 (maybe 114)
c.       What is the general guideline for stability?           - Even #’s more stable than odd #’s.

5.       What is a Curie (definition and constant)? Nuclear disintegrations per unit time occurring in a radioactive material.  Ci = 3.7 x 1010

6.       What is the formula for finding Half-Life?              T1/2 = 0.693
k

7.       What is the formula for finding the Rate of Decay?           Rate = kNt


Organic Chemistry

1.       What are the three basic types of Hydrocarbons?
a.       How reactive are they?
b.      What types of reactions are they typically capable of?
Saturated
Not very reactive
Combustion w/Oxy or Halo
Unsaturated
Very reactive
Addition Reaction, Combustion
Aromatic
Not very reactive
Replacement Reactions


2.       What are the families of each of the three basic types of Hydrocarbons?
a.       What group(s) of carbon families does each include?
b.      What type of electron bond(s) exists for each family?
c.       What is the general formula for each family?

Saturated
Alkanes
C-C chains
CnH(2n+2)
Saturated
Cycloalkanes
C-C rings
CnH(2n)
Unsaturated
Alkene
C=C chain
CnH(2n)
Unsaturated
Alkyne
CC chain
CnH(2n-2)
Aromatic
Benzene
C-C/C=C rings
C6H6


3.       What are the first ten alkanes?
a.       CH4        methane
b.      C2H6      ethane
c.       C3H8      propane
d.      C4H10   butane
e.      C5H12   pentane
f.        C6H14   hexane
g.       C7H16   heptane
h.      C8H18   octane
i.         C9H20   nonane
j.        C10H22 decane

4.       What are the first four alcohols and their chemical formulas?
a.       CH3OH                                  Methanol
b.      CH3CH2OH                          Ethanol
c.       CH3CH2CH2OH                  Propanol
d.      CH3CH2CH2CH2OH          Butanol

5.       What is the difference between a primary, secondary, and tertiary alcohol?
a.       Primary has one Carbon group attached to the carbon attached to the OH group.
                                                               i.      eg.   C-C-C-OH
b.      Secondary has two Carbon groups attached to the carbon attached to the OH group.
c.       Tertiary has three.

6.       Name the following compounds:




7.       What is an Aldehyde (and its suffix)? Suffix = “al”
a.       What is its R-group positioning?

b.      What is its molecular tail?             -CHO
c.       Draw Formaldehyde (methanal)

8.       What is a Ketone (and its suffix)? Suffix = “one”
a.       What is its R-group positioning?

 
b.      What is its molecular tail?  =O

c.       Draw acetone (propone)


9.       What would happen if litmus paper were dipped into an Amine?
a.       It would turn red litmus paper blue.





the end

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